Ceramic Spray Coating SDS
SECTION 1. IDENTIFICATION
Product name Ceramic Spray Coating
Manufacturer or supplier's details
Company Identification
SECTION 2. HAZARDS IDENTIFICATION
Note: This product is a consumer product and is labeled in accordance with the Consumer Product Safety Commission regulations and not OSHA regulations. The requirements for the labeling of consumer products take precedence over OSHA labeling so the actual product label will not contain the OSHA label elements shown below on this SDS.
GHS classification in accordance with 29 CFR 1910.1200
Flammable liquids Category 4
Serious eye damage Category 1
Carcinogenicity Category 2
Specific target organ systemic toxicity - single exposure Category 3
Aspiration hazard Category 1
GHS label elements
Hazard pictograms
Signal Word Danger
Hazard Statements H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H372 Causes damage to organs (Central nervous system) through prolonged or repeated exposure. H373 May cause damage to organs (Liver, Kidney, Auditory system) through prolonged or repeated exposure.
Precautionary Statements Prevention:
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P242 Use only non-sparking tools.
P260 Do not breathe spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P331 Do NOT induce vomiting.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
none
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
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Substance I Mixture |
Mixture |
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Chemical nature |
Inorganic and organic compounds Mixture |
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Hazardous ingredients |
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Chemical Name |
CAS-No. |
Concentration (% w/w) |
|
Stoddard Solvent |
8052-41-3 |
≥ 12.5 - ≤ 25 |
|
Distillates (Petroleum), Hydro Lite |
64742-7-8 |
≥ 25 - ≤ 50 |
|
Tetraisopropoxy Titanate |
546-68-9 |
≥ 3.5 - ≤ 8.5 |
|
Xylene |
1330-20-7 |
≥ 2.5 - ≤ 5.5 |
|
2-Ethvlhexane-1,3-diol |
94-96-2 |
≥ 1 - ≤ 4 |
|
Trimethylbenzene |
25551-13-7 |
≥ 0.6 - ≤ 1.35 |
|
Ethylbenzene |
100-41-4 |
≥ 0.5 - ≤ 1.25 |
|
Cumene |
98-82-8 |
≥ 0.12 - ≤ 0.27 |
|
Napthalane |
91-20-3 |
≥ 0.06 - ≤ 0.14 |
|
Nonane |
111-84-2 |
≥ 0.6 - ≤ 1.35 |
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|
|
SECTION 4. FIRST AID MEASURES
General advice In the case of accident or if you feel unwell, seek medical advice immediately.
When symptoms persist or in all cases of doubt seek medical advice.
If inhaled If inhaled, remove to fresh air.
Get medical attention.
In case of skin contact In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Get medical attention. Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed If swallowed, DO NOT induce vomiting.
If vomiting occurs have person lean forward
Call a Physician or poison control center immediately.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
May be fatal if swallowed and enters airways. Causes serious eye damage.
May cause drowsiness or dizziness. Suspected of causing cancer.
Causes damage to organs through prolonged or repeated exposure.
Prolonged or repeated contact may dry skin and cause irritation.
Protection of First-Aiders First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
Notes to physician treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Water spray
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing Media High volume water jet
Specific hazards during fire Do not use a solid water stream as it may scatter and spread fire.
Fighting Flash back possible over considerable distance.
Vapors may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion production Carbon oxides
Silicon oxides
Formaldehyde
Metal oxides
Specific extinguishing methods Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use Personal protective Equipment.
Personal precautions, Ventilate the area.
protective equipment and Use personal protective equipment
emergency procedures Follow safe handling advice and personal protective equipment recommendations
Environmental precautions Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g., by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for Non-sparking tools should be used.
containment and cleaning up Soak up with inert absorbent material.
Suppress (knock down) gases/vapors/mists with a water spray jet.
For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures ensure all equipment is electrically grounded before beginning transfer operations.
This material can accumulate static charge due to its inherent physical properties and can therefore cause an electrical ignition source to vapors. In order to prevent a fire hazard, as bonding and grounding may be insufficient to remove static electricity, it is necessary to provide an inert gas purge before beginning transfer operations.
Restrict flow velocity in order to reduce the accumulation of static electricity.
Local/Total ventilation Use with local exhaust ventilation.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential.
Advice on safe handling Do not get on skin or clothing.
Do not breathe vapors or spray mist. Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety
Practice, based on the results of the workplace exposure
Assessment.
Non-sparking tools should be used. Keep container tightly closed.
Keep away from water. Protect from moisture.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage Keep in properly labeled containers. Store locked up.
Keep tightly closed.
Keep in a cool, well-ventilated place.
Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid Do not store with the following product types: Strong oxidizing agents
Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures which in contact with water emit flammable gases
Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
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Ingredients |
CAS-No. |
Value type (Form of exposure) |
Control parame- ters I Permissible concentration |
Basis |
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Stoddard solvent |
8052-41-3 |
TWA |
100 ppm |
ACGIH |
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TWA |
350 mg/m3 |
NIOSH REL |
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C |
1,800 mg/m3 |
NIOSH REL |
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TWA |
500 ppm 2,900 mg/m3 |
OSHA Z-1 |
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Xylene |
1330-20-7 |
TWA |
100 ppm |
OSHAZ-1 |
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435 mg/m3 |
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TWA |
100 ppm |
ACGIH |
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STEL |
150 ppm |
ACGIH |
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Nonane |
111-84-2 |
TWA |
200 ppm |
ACGIH |
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TWA |
200 ppm |
NIOSH REL |
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1,050 mQ/m 3 |
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Trimethylbenzene |
25551-13-7 |
TWA |
25 oom |
ACGIH |
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Ethvlbenzene |
100-41-4 |
TWA |
20 oom |
ACGIH |
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TWA |
100 ppm |
OSHAZ-1 |
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435 mg/m3 |
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TWA |
100 ppm |
NIOSH REL |
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435 mQ/m 3 |
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ST |
125 ppm 545 mqlm3 |
NIOSH REL |
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Cumene |
98-82-8 |
TWA TWA |
50 oom 50 ppm 245 mgl m3 |
ACGIH NIOSH REL |
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Naphthalene |
91-20-3 |
TWA
TWA |
50 ppm 245 malm3 10 ppm |
OSHA Z-1
ACGIH |
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TWA |
10 ppm 50 mglm3 |
NIOSH REL |
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ST |
15 ppm 75 mglm3 |
NIOSH REL |
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TWA |
10 ppm 50 mal m3 |
OSHAZ-1 |
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Hazardous components without workplace control parameters
Ingredients Gas-No
Tetraisopropoxy titanate 546-68-9
2-Ethylhexane-1,3-diol 94-96-2
Occupational exposure limits of decomposition products
Ingredients CAS-No. Value type Control parameters/ Basis
(form of exposure) Permissible concentration
Propan-2-ol 67-63-0 TWA 200 ppm ACGIH
STEL 400 ppm ACGIH
TWA 400 ppm NOSH REL
980 mglm3
ST 500 ppm NIOSH REL
1,225 mglm3
TWA 400 ppm OSHA Z-1
980 mglm3
Biological occupational exposure limits
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Ingredients |
CAS-No. |
Control parameters |
Biological specimen |
Sam- piing time |
Permissible concentra- tion |
Basis |
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Xylene |
1330-20-7 |
Methylhippu ric acids |
Urine |
End of shift (As soon as possible after exposure ceases) |
1.5 gig creatinine |
ACGIH BEi |
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Ethylbenzene |
100-41-4 |
Sum of mandelic acid and phenyl glyoxylic acid |
Urine |
End of shift (As soon as possible after exposure ceases) |
0.15 gig creatinine |
ACGIH BEi |
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Engineering measures Processing may form hazardous compounds (see section |
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10).
Minimize workplace exposure concentrations.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential
Use with local exhaust ventilation.
Dust formation may be relevant in the processing of this product. In addition to substance-specific OELs, general limitations of concentrations of particulates in the air at workplaces have to be considered in workplace risk assessment. Relevant limits include: OSHA PEL for Particulates Not Otherwise Regulated of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for Particles (insoluble or poorly soluble) Not Otherwise Specified of 3 mg/m3 - respirable particles, 10 mg/m3 - inhalable particles.
Personal protective equipment
Respiratory protection General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.
Hand protection Material Chemical-resistant gloves
Remarks Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.
Eye protection Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear face-shiel.
Skin and body protection Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing, unless assessment demonstrates that the risk of explosive atmospheres or flash fires is low.
Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc.).
Hygiene measures ensure that eye flushing systems and safety showers are located close to the working place.
When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.
For further information regarding th use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these type of materials in consumer aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Chemical customer service group.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Color liquid
Odor Hydrocarbon-like
Odor Threshold pH solvent
Melting point/freezing point No data available
Initial boiling point and boiling range 200 – 300 °C (392 – 572 °F)
Flash point 80 – 95.6 °C (176 – 204.1 °F) Method: Tag Closed Cup
Evaporation rate No data available
Flammability (solid, gas) Not applicable
Self-ignition The substance or mixture is not classified as pyrophoric. The substance or mixture is not classified as self-heating.
Upper explosion limit / Upper No data available
Flammability limit
Lower explosion limit / No data available
Lower flammability limit
Vapor pressure No data available
Relative vapor density No data available
Relative density 0.80 – 0.825 @ 15.6 °C (60.1 °F)
Solubility (ies) insoluble
Water solubility
Partition coefficient: No data available
noctanol/water
Auto ignition temperature ›200 °C
Decomposition temperature No data available
Viscosity, kinematic 15 est (25°C)
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size Not applicable
SECTION 10. STABILITY AND REACTIVIT
Reactivity Not classified as a reactivity hazard.
Chemical stability Stable under normal conditions
Possibility of hazardous highly flammable liquid and vapor.
Reactions Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
When heated to temperatures above 150 °C (300 °F) in the presence of air, trace quantities of formaldehyde may be released.
Adequate ventilation is required.
See OSHA formaldehyde standard, 29 CFR 1910.1048 Hazardous decomposition products will be formed upon contact with water or humid air.
Hazardous decomposition products will be formed at elevated temperatures.
Conditions to avoid Exposure to moisture.
Handling operations that can promote accumulation of static charges.
Heat, flames and sparks.
Incompatible Materials Oxidizing agents
Water
Hazardous decomposition products
Contact with water or Humid air Propan-2ol
Thermal decomposition formaldehyde
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Skin contact
Ingestion
Eye contact
Product:
Acute oral toxicity Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Acute Inhalation toxicity Acute toxicity estimate: 120.78 mg /I
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method
Acute dermal toxicity LD50 (Rabbit): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal toxicity
Remarks: On basis of test data
Ingredients:
Stoddard solvent:
Acute oral toxicity LD50 (Rat): > 5,000 mg/kg
Acute Inhalation toxicity LC50 (Rat): > 5.5 mg/I
Exposure time: 4 h
Test atmosphere: vapor
Assessment: The substance or mixture has no acute inhalation toxicity
Acute Thermal Toxicity LD50:> 5,000mg/kg
Tetraisopropoxy titanate:
Acute oral toxicity LD50 (Rat): > 5,000 mg/kg
Acute Inhalation toxicity LC50 (Rat): > 37.4 mg/I
Exposure time: 4 h
Test atmosphere: vapor
Remarks: Based on data from similar material
Acute Thermal Toxicity LD50(Rabbit) >5,000mg/kg
Remarks: Based on data from similar material
Xylene:
Acute oral toxicity LD50 (Rat): > 4,300 mg/kg
Method: Directive 67/548/EEC, Annex V, 8.11
Acute Inhalation toxicity LC50 (Rat): > 27.5 mg/I
Exposure time: 4 h
Test atmosphere: vapor
Acute toxicity estimate: 11 mg/I Exposure time: 4 h
Test atmosphere: vapor
Method: Expert judgment
Remarks: Based on harmonized classification in EU regulation 1272/2008, Annex VI
Acute Thermal Toxicity Acute toxicity estimate: 1,100 mg/kg Method: Expert judgment
Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI
2-Ethylhexane-1,3-diol:
Acute oral toxicity LD50 (Rat): > 5,000 mg/kg
Acute dermal toxicity LD50 (Rabbit): > 5,000 mg/kg
Nonane:
Acute oral toxicity LD50 (Rat):> 5,000 mg/kg
Remarks: Based on data from similar materials
Acute dermal toxicity LD50 (Rabbit): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal toxicity
Remarks: Based on data from similar materials
Trimethylbenzene:
Acute oral toxicity LD50 (Rat): 6,000 mg/kg
Remarks: Based on data from similar materials
Acute dermal toxicity LD50 (Rat): > 3,440 mg/kg
Assessment: The substance or mixture has no acute dermal toxicity
Remarks: Based on data from similar materials
Ethylbenzene:
Acute oral toxicity LD50 (Rat): 3,500 mg/kg
Acute inhalation toxicity LC50 (Rat): 17.2 mg/I
Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity LD50 (Rabbit): > 5,000 mg/kg
Cumene:
Acute oral toxicity LD50 (Rat): 2,700 mg/kg
Acute dermal toxicity LD50 (Rabbit): > 5,000 mg/kg
Naphthalene:
Acute oral toxicity LD50 (Mouse): 553 mg/kg
Method: OECD Test Guideline 401
Acute inhalation toxicity LC50 (Rat): > 0.4 mg/I
Exposure time: 4 h Test atmosphere: vapor
Method: OECD Test Guideline 403
Acute dermal toxicity LD50 (Rat): > 2,500 mg/kg
Assessment: The substance or mixture has no acute dermal toxicity
Skin corrosion/irritation
Not classified based on available information.
Product:
Species: Rabbit
Result: Mild skin irritation Remarks: On basis of test data.
Ingredients:
Stoddard solvent:
Assessment: Repeated exposure may cause skin dryness or cracking.
Tetraisopropoxy titanate:
Rabbit
Result: No skin irritation
Xylene:
Species: Rabbit
Result: Skin Irritation
Trimethylbenzene:
Species: Rabbit
Result: Skin irritation
Remarks: Based on data from similar materials
Cumene
Species: Rabbit
Result: No skin irritation
Naphthalene
Species: Rabbit
Method: OECD Test Guideline 404
Result: No skin irritation
Serious eye damage/eye irritation
Causes serious eye damage.
Ingredients:
Stoddard solvent:
Species: Rabbit
Result: No eye irritation
Tetraisopropoxy titanate:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Xylene:
Species: Rabbit
Result: Irritation to eyes, reversing within 7 days
2-Ethylhexane-1,3-diol:
Species: Rabbit
Result: Irreversible effects on the eye
Nonane:
Species: Rabbit Result: No eye irritation
Remarks: Based on data from similar materials
Trimethylbenzene:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Remarks: Based on data from similar materials
Ethylbenzene:
Species: Rabbit
Result: No eye irritation
Cumene:
Species:Rabbit Result: No eye irritation
Naphthalene:
Guinea pig Result: No eye irritation
Method: OECD Test Guideline 405
Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Ingredients:
Stoddard solvent:
Routes of exposure: Skin contact Species: Guinea pig
Result: negative
Tetraisopropoxy titanate:
Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig
Method: OECD Test Guideline 406 Result: negative
Xylene:
Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact
Species: Mouse
Method: OECD Test Guideline 429 Result: negative
Nonane:
Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials
Trimethylbenzene:
Test Type: Maximization
Test Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials
Ethylbenzene:
Test Type: Human repeat insult patch test (HRIPT) Routes of exposure: Skin contact
Result: negative
Cumene:
Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig
Result: negative
Naphthalene
Test Type: Maximization Test Routes of exposure: Skin contact Species: Guinea pig
Method: OECD Test Guideline 406 Result: negative
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Stoddard solvent:
Genotoxicity in vitro Test Type: In vitro mammalian cell gene mutation test
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vivo Test Type: Rodent dominant lethal test (germ cell} (in vivo)
Species: Mouse
Application Route: intraperitoneal injection
Result: negative
Remarks: Based on data from similar materials
Tetraisopropoxy titanate
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay)
Species: Mouse
Application Route: intraperitoneal injection
Result: negative
Remarks: Based on data from similar materials
Xylene:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro Result: negative
Test Type: In vitro sister chromatid exchange assay in mammalian cells
Result: negative
Penotoxicity in vivo Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Mouse
Application Route: Skin contact
Result: negative
Nonane:
renotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Trimethylbenzene:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: Based on data from similar materials
Genotoxicity in vitro Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay)
Species: Mouse
Application Route: intraperitoneal injection
Result: negative
Remarks: Based on data from similar materials
Ethylbenzene:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Genotoxicity in vitro Test Type: Unscheduled DNA synthesis (UDS) test with mammalian liver cells in vivo
Species: Mouse
Application Route: Inhalation
Method: OECD Test Guideline 486
Result: negative
Cumene:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative
Genotoxicity in vitro Test Type: In vivo micronucleus test
Species: Mouse
Application Route: intraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Naphthalene
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Test Type: Chromosome aberration test in vitro
Result: positive
Genotoxicity in vitro Test Type: Unscheduled DNA synthesis (UDS) test with mammalian liver cells in vivo
Species: Rat
Application Route: Ingestion
Result: negative
Carcinogenicity
Suspected of causing cancer.
Ingredients:
Tetraisopropoxy titanate:
Species: Rat
Application Route: inhalation (vapor)
Exposure time: 104 weeks
Result: negative
Remarks: Based on data from similar materials
Xylene:
Species: Rat
Application Route: Ingestion
Exposure time: 103 weeks
Result: negative
Ethylbenzene:
Species: Rat
Application Route: Inhalation
Exposure time: 104 weeks
Result: positive
Remarks: The mechanism or mode of action may not be relevant in humans.
Cumene:
Species: Rat
Application Route: inhalation (gas)
Exposure time: 105 weeks
Result: negative
Naphthalene:
Species: Rat
Application Route: inhalation (vapor)
Exposure time: 105 weeks
IARC Limited evidence of carcinogenicity in animal studies
Group 2B: Possibly carcinogenic to humans
Ethylbenzene 100-41-4
Cumene 98-82-8
Naphthalene 91-20-3
OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA's list of regulated carcinogens.
NTP Reasonably anticipated to be a human carcinogen
Cumene 98-82-8
Naphthalene 91-20-3
Reproductive toxicity
Not classified based on available information.
Ingredients:
Tetraisopropoxy titanate:
Effects on fetal development Test Type: Embryo-fetal development
Species: Rabbit
Application Route: Ingestion
Result: negative
Remarks: Based on data from similar materials
Xylene:
Effects on fertility Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Effects on fetal development Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor) Method: OECD Test Guideline 416
Result: negative
Remarks: Based on data from similar materials
Nonane:
Effects on fertility Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor) Method: OECD Test Guideline 416
Result: negative
Remarks: Based on data from similar materials
Trimethylbenzene:
Effects on fertility Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor) Method: OECD Test Guideline 416
Result: negative
Remarks: Based on data from similar materials
Effects on fetal development Test Type: Embryo-fetal development
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Remarks: Based on data from similar materials
Ethylbenzene:
Effects on fertility Test Type: Two-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor)
Method: OECD Test Guideline 415
Result: negative
Effects on fetal development Test Type: Embryo-fetal development
Species: Rat
Application Route: Inhalation
Method: OECD Test Guideline 414
Result: negative
Cumene:
Effects on fertility Species: Rat, male
Application Route: inhalation (vapor)
Result: negative
Effects on fetal development Test Type: Embryo-fetal development
Species: Rat
Application Route: inhalation (vapor)
Method: OECD Test Guideline 414
Result: negative
Naphthalene:
Effects on fetal development Test Type: Embryo-fetal development
Species: Rabbit
Application Route: Ingestion
Method: OECD Test Guideline 414
Result: negative
STOT-single exposure
May cause drowsiness or dizziness.
Ingredients:
Stoddard solvent:
Assessment: May cause drowsiness or dizziness.
Tetraisopropoxy titanate:
Assessment: May cause drowsiness or dizziness.
Xylene:
Assessment: May cause respiratory irritation.
Nonane:
Assessment: May cause drowsiness or dizziness.
Trimethylbenzene:
Assessment: May cause respiratory irritation., May cause drowsiness or dizziness. Remarks: Based on data from similar materials
Cumene:
Assessment: May cause respiratory irritation.
STOT-repeated exposure
Causes damage to organs (Central nervous system) through prolonged or repeated exposure. May cause damage to organs (Liver, Kidney, Auditory system) through prolonged or repeated exposure.
Ingredients:
Stoddard solvent:
Target Organs: Central nervous system
Assessment: Causes damage to organs through prolonged or repeated exposure.
Xylene:
Routes of exposure: inhalation (vapor)
Target Organs: Central nervous system, Liver, Kidney
Assessment: Shown to produce significant health effects in animals at concentrations of >0.2 to 1 mg/I/6h/d.
Ethylbenzene:
Routes of exposure: inhalation (vapor) Target Organs: Auditory system
Assessment: Shown to produce significant health effects in animals at concentrations of >0.2 to
1 mg/I/6h/d.
Naphthalene:
Exposure: inhalation (vapor)
Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or less.
Repeated dose toxicity
Ingredients:
Stoddard solvent:
Species: Rat NOAEL: 2.34 mg/I
LOAEL: 4.67 mg/I
Application Route: inhalation (vapor)
Exposure time: 6 Months
Tetraisopropoxy titanate:
Species: Rat NOAEL: 12.3 mg/I
Application Route: inhalation (vapor)
Exposure time: 13 Weeks
Method: OECD Test Guideline 413
Remarks: Based on data from similar materials
Xylene:
Species: Rat NOAEL: 4.35 mg/I
Application Route: inhalation (vapor)
Exposure time: 90 Days
Nonane:
Species: Rat NOAEL: 100 mg/kg
Application Route: Ingestion
Exposure time: 90 Days
Method: OECD Test Guideline 408
Sp ec i es : Rat NOAEL: 8.4 mg/I
Application Route: inhalation (vapor)
Exposure time: 13 Weeks
Trimethylbenzene:
Species: Rat NOAEL: 1.8 mg/I
Application Route: inhalation (vapor)
Exposure time: 12 Months
Remarks: Based on data from similar materials
Ethylbenzene:
Species: Rat, female LOAEL: 75 ppm
Application Route: inhalation (vapor)
Exposure time: 104 Weeks
Cumene:
Species: Rat NOAEL: 125 ppm
LOAEL: 250 ppm
Application Route: inhalation (vapor)
Exposure time: 90 Days
Naphthalene:
Species: Mouse NOAEL: 133 mg/kg
Application Route: Ingestion
Exposure time: 90 Days
Method: OECD Test Guideline 408
Species: Rat NOAEL: 0.011 mg/I
Application Route: inhalation (vapor) Exposure time: 13 Weeks
Method: OECD Test Guideline 413
Species: Rat NOAEL: 300 mg/kg
Application Route: Skin contact Exposure time: 13 Weeks
Method: OECD Test Guideline 411
Aspiration toxicity
May be fatal if swallowed and enters airways.
Ingredients:
Stoddard solvent:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
Xylene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
Nonane:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
Trimethylbenzene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity y hazard.
Ethylbenzene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
Cumene:
The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard.
Experience with human exposure
Ingredients:
Stoddard solvent:
Inhalation Target Organs: Central nervous system
Symptoms: Dizziness, Headache, Neurological disorders
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Stoddard solvent:
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 1.4 mg/I Exposure time: 48 h
aquatic invertebrates Test substance: Water Accommodated Fraction
Toxicity to algae EC50 (Pseudokirchneriella subcapitata (green algae)): 1.2 mg/I
Exposure time: 72 h
Toxicity to daphnia and other NOELR (Daphnia magna (Water flea)): 0.097 mg/I Exposure time: 21 d
aquatic invertebrates Method: OECD Test Guideline 211
(Chronic toxicity) Remarks: Based on data from similar materials
Tetraisopropoxy titanate:
Toxicity to fish LC50 (Pimephales promelas (fathead minnow)): > 100 mg/I Exposure time: 96 h
Remarks: Based on data from similar materials
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 100 mg/I Exposure time: 48 h
aquatic invertebrates Method: OECD Test Guideline 202
Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)):> 100 mg/I Exposure time: 72 h
Method: OECD Test Guideline 201
Xylene:
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): 2.6 mg/I Exposure time: 96 h
Method: OECD Test Guideline 203
Remarks: Based on data from similar materials
aquatic invertebrates Exposure time: 24 h
Method: OECD Test Guideline 202
Remarks: Based on data from similar materials
Toxicity to algae EC10 (Pseudokirchneriella subcapitata (green algae)): 1.9 mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials
Toxicity to fish (Chronic toxicity) NOEC (Oncorhynchus mykiss (rainbow trout)): > 1.3 mg/I
Exposure time: 56 d
Toxicity to daphnia and other EC10 (Daphnia magna (Water flea)): 1.91 mg/I
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Method: OECD Test Guideline 211
Remarks: Based on data from similar materials
Toxicity to microorganisms EC50: > 157 mg/I
Exposure time: 3 h
Method: OECD Test Guideline 209
Remarks: Based on data from similar materials
2-Ethylhexane-1,3-diol:
Toxicity to fish LC50 (lctalurus punctatus (channel catfish)): 624 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 100 mg/I
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)):> 100 mg/I
Exposure time: 72 h
Method: OECD Test Guideline201
Nonane:
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 0.2 mg/I
Exposure time: 48 h
aquatic invertebrates
M-Factor (Acute aquatic toxicity)
M-Factor (Chronic aquatic toxicity)
Trimethylbenzene:
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 3.6 mg/I
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials
Ethylbenzene:
Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): 4.2 mg/I
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 1.8 - 2.4 mg/I
aquatic invertebrates Exposure time: 48 h
Toxicity to algae EC50 (Pseudokirchneriella subcapitata (green algae)): 5.4 mg/I
Exposure time: 72 h
Toxicity to daphnia and other NOEC (Ceriodaphnia dubia (water flea)): 0.96 mg/I
aquatic invertebrates Exposure time: 7 d
(Chronic toxicity)
Toxicity to microorganisms EC50 (Nitrosomonas sp.): 96 mg/I
Exposure time: 24 h
Method: OECD Test Guideline 209
Cumene:
Toxicity to fish LC50 (Oncorhynchus mykiss(rainbow trout)): 4.8 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 2.14 mg/I
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae ErC50 (Desmodesmus subspicatus (green algae)): 2.01 mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201
EC10 (Desmodesmus subspicatus (green algae)): 1.35 mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and other NOEC (Daphnia magna (Water flea)): 0.35 mg/I
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity)
Naphthalene:
Toxicity to fish LC50 (Pimephales promelas (fathead minnow)): 6.08 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 2.16 mg/I
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae EC50 (Skeletonema costatum (marine diatom)): 0.4 mg/I
Exposure time: 72 h
M-Factor (Acute aquatic toxicity)
Toxicity to fish (Chronic toxicity) NOEC (Oncorhynchus kisutch (coho salmon)): 0.37 mg/I
Exposure time: 40 d
Toxicity to daphnia and other NOEC (Daphnia pulex (Water flea)): 0.59 mg/I
aquatic invertebrates Exposure time : 125 d
(Chronic toxicity)
Toxicity to microorganisms IC50 (Nitrosomonas sp.): 29 mg/I Exposure time: 24 h
Persistence and degradability
Ingredients:
Stoddard solvent:
Biodegradability Result: Readily biodegradable.
Biodegradation: 75 %
Exposure time: 28 d
Tetraisopropoxy titanate:
Biodegradability Result: Readily biodegradable.
Biodegradation: 78 %
Exposure time: 20 d
Remarks: Based on data from similar materials
Xylene:
Biodegradability Result: Readily biodegradable.
Biodegradation: 87.8 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Remarks: Based on data from similar materials
2-Ethylhexane-1,3-diol :
Biodegradability Result: Readily biodegradable.
Biodegradation: 93 %
Exposure time: 28 d
Method: OECD Test Guideline 301
Nonane:
Biodegradability Result: Readily biodegradable.
Biodegradation: 100 %
Exposure time: 25 d
Trimethylbenzene:
Biodegradability Result: Not readily biodegradable.
Biodegradation: 4 - 18 %
Exposure time: 28 d
Method: OECD Test Guideline 301C
Remarks: Based on data from similar materials
Ethylbenzene:
Biodegradability Result: Readily biodegradable.
Biodegradation: 70 - 80 %
Exposure time: 28 d
Cumene:
Biodegradability Result: Readily biodegradable.
Biodegradation: 70 % E
Exposure time: 20 d
Naphthalene:
Biodegradability Result: Not readily biodegradable.
Biodegradation: 2 %
Exposure time: 4 Weeks
Method: OECD Test Guideline 302
Bioaccumulative potential
Ingredients:
Stoddard solvent:
Partition coefficient: n log Pow:> 4
octanol/water Remarks: Expert judgment
Xylene:
Bioaccumulation Species: Oncorhynchus mykiss (rainbow trout)
Bio concentration factor (BCF): 5.4 - 25.9
Partition coefficient: log Pow: 3.12 - 3.2
noctanol/water
Nonane:
Partition coefficient: log Pow: 5.65
noctanol/water
Trimethylbenzene:
Partition coefficient: og Pow: > 3.5
noctanol/water Remarks: Based on data from similar materials
Ethylbenzene:
Bioaccumulation Species: Fish
Bio-concentration factor (BCF): < 100
Remarks: Based on data from similar material
Partition coefficient: log Pow: 3.6
noctanol/water
Cumene:
Partition coefficient: log Pow: 3.55
noctanol/water
Naphthalene:
Bioaccumulation Species: Cyprinus carpio (Carp)
Bio concentration factor (BCF): 36.5 - 168
Method: OECD Test Guideline 305
Partition coefficient: log Pow: 3.4
noctanol/water
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Resource Conservation and when a decision is made to discard this material as supplied,
Recovery Act (RCRA) it is classified as a RCRA hazardous waste
Waste Code 0001: ignitability
0018
Waste from residues Dispose of in accordance with local regulations
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Empty containers retain residue and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other
Sources of ignition. They may explode and cause injury and/or death.
If not otherwise specified: Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
DOT (Department of Transportation):
UN1268, Petroleum Distillates, N.O.S., CBL, III
IATA (International Air Transport Association): Not regulated as a dangerous good.
IMDG-Code: Not regulated as a dangerous good.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards Fire Hazard
Hazard not otherwise classified (physical hazards)
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Aspiration hazard
SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Tittle III, section 313.
US State Regulations
Pennsylvania Right to know
Stoddard solvent 8052-41-3
Trimethylated silica 68988-56-7
Dimethyl siloxane, trimethylsiloxy-terminated 63148-62-9
Tetraisopropoxy titanate 546-68-9
Xylene 1330-20-7
2-Ethylhexane-1,3-diol 94-96-2
Nonane 111-84-2
Trimethylbenzene 25551-13-7
Ethylbenzene 100-41-4
Cumene 98-82-8
Naphthalene 91-20-3
Propan-2-ol 67-63-0
Toluene 108-88-3
California Prop. 65
WARNING: This product can expose you to chemicals including Ethylbenzene, Cumene, Naphthalene, Benzene, which is/are known to the State of California to cause cancer, and Toluene, Benzene, which is/are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
California List of Hazardous Substances
Stoddard Solvent 8052-41-3
Xylene 1330-20-7
California Permissible Exposure Limits for Chemical Contaminants
Stoddard solvent 8052-41-3
Xylene 1330-20-7
Nonane 111-84-2
Trimethylbenzene 25551-13-7
Ethylbenzene 100-41-4
The Ingredients of this product are reported in the following inventories:
Currently pre/registered or exempt under REACH. Please refer to section 1 for recommended uses. For purchases from non-EU Dow Chemical legal entities with the intention to export into EEA please contact your DC representative/local office.
TSCA All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
AICS All ingredients listed or exempt.
IECSC All ingredients listed or exempt.
KECI All ingredients listed, exempt or notified.
PICCS All ingredients listed or exempt.
DSL All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
TCSI All ingredients listed or exempt.
SECTION 16. OTHER INFORMATION
2
2
1
1
2
2
1
1
USA. ACGIH Threshold Limit Values (TLV)
ACGIH - Biological Exposure Indices (BEi)
USA. NIOSH Recommended Exposure Limits
USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim its for Air Contaminants
8-hour, time-weighted average
Short-term exposure limit
NIOSH REL/TWA Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek
NIOSH REL/ ST STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday
NIOSH REL /C Ceiling value not be exceeded at any time.
OSHA Z-1 / TWA 8-hour time weighted average
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardization; DOT - Department of Transportation; DSL - Domestic Sub stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organization for Standardization; KECI - Ko rea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50
- Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration;
n.o.s. - Not otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Ob served (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZloC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bio accumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorization and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bio accumulative.
Sources of key data used internal technical data, data from raw material SDSs, OECD eChem Portal search results
to compile the Material and European Chemicals Agency http://echa.europa.eu/
Safety Data Sheet
Revision Date 4/01/2019
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SOS material in the user's end product, if applicable.
Proje' Car Care Products
15020 Desman Rd
La Mirada CA 90638
United States
(562) 922-2708
support@projeproducts.com